QUALITY OF HEAT
(b) A block of metal of mass 300g at 1000c is dropped into a logged calorimeter of heat capacity 40Jk-1, containing 200g of water at 200c. The temperature of the resulting mixture is 340c. (Specific heat capacity of water = 4200Jkg-1k-1)
Determine:
(i) Heat gained by calorimeter.
(ii) Heat gained by water.
(iii) Heat lost by the metal block.
(iv) Specific heat capacity of the metal block.
(b) 200g of a solid was uniformly heated by a 0.2 kw heater for sometime. The graph in the figure below shows how the temperature of the solid changed with time.
(i) Explain what is happening between OA and AB.
(ii) Calculate the specific heat capacity of the solid.
(iii) Calculate the specific latent heat of fusion k of the solid.
Determine;-
(i) Heat gained by calorimeter
(ii) Heat gained by water
(iii) Heat lost by the metal block
(iv) Specific heat capacity of the metal block
(b) A jet delivering 0.44g of dry steam per second, at 100oC is directed on to crushed ice at 0.0oC contained in an unlagged copper can which has a hole in the base. 4.44g of water at 0.0oC flow out of the hole per second
(c) Figure 7 below shows a cross-section of a vacuum flask
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(i) Name the parts labelled A and B on the diagram
(ii) Explain how the heat losses are minimized when hot liquid is poured into the flask
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State with a reason the observations made after some time
(b) Figure 3 shows a test tube partially filled with water. An ice wrapped in wire gauze is
placed at the bottom of the test-tube. It is then held in the flame of a bunsen burner as
shown below
fig. 3
State and explain what will be observed after some time
Calculate the time taken
(b) 0.5kg of naphthalene contained in an aluminium can of mass 0.4kg is melted in a water bath and raised to a temperature of 100oC. Calculate the total heat given out when the can and its contents are allowed to cool to room temperature, 20oC. Neglect losses by evaporation during heating process and give your answer to the nearest kilojoule.
(For naphthalene melting point = 80oC , Specific heat capacity for both liquid and
solid =2100J/KgK; specific latent heat of fusion = 170000J/Kg.
For aluminium: specific heat capacity = 900J/Kgk
(c) Briefly explain two ways other than direct heating by which quantity of liquid may be made to evaporate more quickly
(d) The diagram below shows a charcoal refrigerator
(i) Explain why charcoal is used and why it is sprinkled with water
(ii) What is the role of the metallic tank and the wire mesh
Latent heat of fusion =334kJ-1
Specific heat capacity of ice= 2,260J kg -1 K -1
Specific heat capacity of water = 4, 200J kg-1 K-1
Latent heat of vaporization = 2, 260KJ kg -1 K -1
Calculate the minimum time required for this activity.
Calculate; –
of a liquid in a vapour phase.
Mass of calorimeter = 50g
Initial mass of water = 70g
Final mass of calorimeter + water + condensed steam = 123g
Final temperature of mixture = 300C
(Specific heat capacity of water = 4200 J kg -1K and specific heat capacity for copper = 390 J kg -1 K-1)
Determine the
iii) Given that L is the specific latent heat of evaporation of steam
(i) State the reason for using a volatile liquid.
(ii) Explain how the volatile liquid is made to vaporize in the cooling compartment and to condense in the cooling fins.
(iii) Explain how cooling takes place in the refrigerator.
(iv) What is the purpose of the double wall?
iii) Determine the value of T.
Use the information above to calculate the energy absorbed by the water every second as it passes through the boiler
Use the same information above to calculate the mass of oil which would need to be burnt in order to provide this energy.
He took the reading M, of the balance at a given time interval. He obtained the following data
| Mass (g) | 100 | 97 | 95 | 93 | 91 | 81 |
| Time (s) | 0 | 135 | 210 | 330 | 405 | 495 |
(a) Plot a graph of mass against time
A filter funnel, a thermometer, a stop watch, ice at 0°C, an immersion heater rated P watts, a beaker, a stand, boss and clamp and a weighing machine.
Describe an experiment to determine the specific latent heat of fusion of ice. Clearly state the measurements to be made.
(b) 200 g of ice at 0°C is added to 400g water in a well lagged calorimeter of mass 40g. The initial temperature of the water was 40°C. If the final temperature of the mixture is X°C, (Specific latent of fusion of ice L = 3.36 x 105 Jkg-1, specific heat capacity of water, c = 4200Jkg-1K-1, specific heat capacity of copper = 400 Jkg-1K-1.)
(i) Derive an expression for the amount of heat gained by ice to melt it and raise its temperature to X°C
(ii) Derive an expression for the amount of heat lost by the calorimeter and its content when their temperature falls to X°C.
(iii) Determine the value of X.
(c) A hydrogen balloon of volume 1.2 m3 is released at the ground level where the pressure is 680 mmHg and a temperature of 20 °C. Determine the volume of the balloon at a height of 2500m above the ground where the pressure drops to 500 mmHg and the temperature is 4°C.
(b) Water of mass 400g at a temperature of 60oC is put in a well lagged copper calorimeter of mass 160g. A piece of ice at 0oC and mass 40g is placed in the calorimeter and the mixture stirred gently until all the ice melts. The final temperature, T, of the mixture is then measured. Determine;
(b) Briefly describe an experiment to determine the specific heat capacity of a liquid substance using the electrical method.
(c) An immersion heater rated 1000W is used to heat a block of ice of mass 500g initially at -10°C until the all the water evaporates at 95°C. Assuming that all the heat supplied is used to heat the ice, calculate the time in minutes for the whole process to take place. (Take specific heat capacity of water as 4200J/KgK, specfic heat capacity of ice = 2100J/Kg K specific latent heat of fusion = 3.35 x 105 J/Kg and specific latent heat of vapourization 2.26 x 105J/Kg)
The following measurements were made:
Mass of calorimeter = 50g
Initial mass of water = 70g
Initial temperature of water = 5oc
Final mass of water + Calorimeter + condensed steam = 123g
Final temperature of mixture = 30oc
Specific heat capacity of water = 4200jkg-1k-1
Specific heat capacity of copper = 390k kg-1k-1
(i)Mass of condensed steam
(ii)Heat gained by water and calorimeter
(ii) Given that L is the specific latent heat of vaporization of steam
(i) Write an expression for the heat given out by steam
(ii)Determine the value of L
(b) Define specific heat capacity
(c) The figure below shows a graph of temperature against time for a given substance (water)
State what happens in the section labelled
(d) A hot-water tank for a house contains 150kg of water at 150C. the tank itself has a heat capacity of 6000 JK-1. an immersion heater is used to heat the water to 500c. the tank is well insulated and the power of the heater is 2500W (specific heat capacity of water =4200 JKg-1K-1
| Time | 2 | |||||||||
| Temperature |
(b) In an experiment to determine the specific latent heat of vaporization of water,
steam at 1000C was passed into water contained in a well lagged copper calorimeter.
The following measurements were made
Mass of calorimeter = 50g
Initial mass of water = 70g
Initial temperature of water = 50C
Final mass of calorimeter + water + condensed steam = 123g
Final temperature of mixture = 300C
Specific heat capacity of water is 4200JKg-1k-1 and specific heat capacity of copper is 390JKg-1k-1 )
(I) Determine the:-
(i) Mass of condensed steam.
(ii) Heat gained by the calorimeter and water.
(II) Given that L is the specific latent heat of vaporization of steam.
(i) Write an expression for the heat given out by the steam.
(ii) Determine the value of L.
(b) Water of mass 200g at a temperature of 60oC is put in a well lagged copper calorimeter of mass 80g. A piece of ice at 0oC and mass 20g is placed in the calorimeter and the mixture stirred gently until all the ice melts. The final temperature of the mixture is then measured
(Latent heat of fusion of ice = 33400Jkg-1, specific heat capacity of water = 4200Jkg-1K-1)
Determine:
(i) State the measurements to be taken in order to achieve the aim of the experiment.
(ii) State the conclusion from the observations made in the figure b(i) above.
II a) Why are the elements of domestic heating appliances made of nichrome
wire instead of tangsten wire.
Calculate
iii) The mass of cold water used
(b) The setup shown below was used to determine the specific latent heat of vapourisation of water.
Describe how you would use the apparatus to determine the specific latent heat of vapourisation of water stating any assumption made and the measurements one would take.
(c) 50g of steam at 100oC was passed into cold water at 20oC. The temperature on the water rose to 60oC. Determine the mass of cold water used (specific heat capacity of water = 4200J/KgK and specific latent heat of vapourisation of water = 2.26 x 106 JKg-1)
iii) Calculate the specific latent heat of fusion of ice
(b) In an experiment to determine the specific latent heat of vaporization of water, steam at 100°c was passed into water contained in a well lagged copper calorimeter.
The following measurements were made:
Mass of calorimeter = 50g
Initial mass of water =70g
Initial temperature of water = 5°c
Final mass of water + Calorimeter + condensed steam =123g
Final temperature of mixture =30°c
Specific heat capacity of water = 4200Jkg-1k-1
Specific heat capacity of copper =390J kg-1k-1
(a) Determine the
(i)Mass of condensed steam
(ii)Heat gained by water and calorimeter.
(b) Given that L is the specific latent heat of vaporization of steam
(i) Write an expression for the heat given out by steam.
(ii)Determine the value of L
of the mixture.
Fig. 11
Specific heat capacity of water = 4200 J Kg-1K-1
Specific latent heat of fusion of ice = 340,000 Jkg-1
Mass of calorimeter = 80g
Initial mass of water = 70g
Initial temperature of water = 5°C
Final mass of calorimeter + water +condensed steam = I 56g
Final temperature of mixture = 30°C
Specific heat capacity of water = 4200JKg-1K-1and specific heat capacity for copper = 390J/Kg-1K-1)
(i) Determine the:
(I) Mass of condensed steam
(II) Heat gained by the calorimeter and water
(ii) Given that L. is the specific latent heat of vaporization of steam
(I) Write an expression for the heat given out by steam.
(II) Determine the value of L
Latent heat of fusion = 334KJkg-1
Specific heat capacity of ice=2100Jkg-1k-1
Specific heat capacity of water=4200Jkg-1K-1
Latent heat of vaporization=2260KJkg-1
(i) Calculate the minimum time required for this activity.
(ii) Explain why the time calculated in (i) above is minimum.
(b) A 200g mass of ice at -14°C was slowly heated by an electric heater of power 30w. The graph below shows how the temperature varies with time.
From the graph above, determine the time corresponding to:
(i) The line QR.
(ii) The line RS
(iii) Hence label the time axis with suitable values and units.
Specific heat capacity of water = 4200J/kgK
Specific latent heat of fusion of ice = 336000J/kgK
(c) Determine a value for the specific heat capacity of ice
(d) Explain why it would be faster to cook food using a Sufuria with an air tight lid than one which is open when at the top of a high mountain.
(b) Figure 10 below shows a block of ice with two heavy weights hanging such that the copper wire connecting them passes over the block.
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(i) It is observed that the wire gradually cuts through the ice block, but leaves it as one piece. Explain.
(ii) What change would be observed if the copper wire used in the experiment was placed by a cotton thread?
(c) A block of ice of mass 40g at 0oC is placed in a calorimeter containing 400g of water at 20oC. The heat absorbed by the calorimeter is negligible. The final temperature of the mixture after all the ice has melted is T. (specific latent heat of fusion of ice=340,000 J/kg, specific heat capacity of water=4200JKg-1k-1)
(d) State two differences between boiling and evaporation.
(b) In an experiment to determine the specific latent heat of vaporization of a liquid using an electrical method, the amount of heat, Q, required to vaporize a given mass, m, of a liquid were recorded as shown in table 2.
| Q (J) X 103 | 3.0 | 4.0 | 5.0 | 6.0 | 7.0 | 8.0 |
| M (kg) X10-3 | 4.0 | 6.4 | 8.8 | 11.2 | 13.6 | 16.0 |
(i) On the grid provided plot a graph of Q (y-axis) against m.
(ii) From the graph, determine the specific latent heat of vaporization of the liquid.
(iii) Suggest a reason why the graph does not pass through the origin.
(iv) Write a possible equation of this graph.
(c) Calculate the amount of heat required to melt 30g of ice at 0oC. (Latent heat of fusion of ice is 3.34 x 105 Jkg-1). Give your answer correct to two decimal places.
(i) Name the substance
(ii) State one disadvantage of this behaviour.
(b) The figure 6 below shows four brass pins pressed on a cooking stuck until they are flat on the wood. A white gummed paper was then stuck on the wood covering the pins. The stick was then passed over a Bunsen flame a few times.
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It was observed that the paper got charred leaving four white spots. Explain this observation.
(c) The figure 7 below shows an experiment carried out by form one students.
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Fig 7
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(i)The students dipped two iron rods of the same length but different thickness into a beaker of hot water at the same time. What was the experiment about?
(ii) State and explain the observations made after about 10 minutes.
(iii) If the two rods were much longer, state and explain any difference from C (ii) above that would be made in the observation.
(b) State two factors which affect freezing point of ice.
(c) Figure 9 below illustrates an experiment in which electrical energy is used to determine specific latent heat of fusion.
Fig 9
(d) In a similar experiment, the following readings were obtained when the heater was switched on for 5 minutes
Voltmeter reading = 6.0V
Ammeter reading = 1.25 A
Temperature rise reading = 10oC
If by the end of the experiment, 200g of water at 0oC was collected determine the latent heat of fusion of ice.
Figure 8
iii) In such an experiment a heater rated 2500w was switched on for 2 minutes. Within this time the temperature of the block rose from 16º C to 186º C. If the block has a mass of 2kg, what is the specific heat capacity of aluminum?
(b) A student decides to measure the specific heat capacity of aluminium by an electrical method. He selects his apparatus and then assembles the aluminium block, the thermometer and the heating element as shown.
The student intends to substitute his results into the relationship mcT VIt
(i) Draw a diagram of the electrical circuit he would need to set up in order to be able to carry out the experiment.
(ii) What other pieces of apparatus would he need?
(iii) He carries out the experiment and then calculates his value for the specific heat capacity of aluminium. He discovers that his value is higher than the accepted value of 900 J kg-’ K-i. Suggest why his result is higher than 900 J kg-1 K-1 .
(iv) With reference to the apparatus shown in the diagram, state two modifications that he should make in order to minimise the discrepancy.
1……………………
2……………………
(c ) If the specific latent heat of ice is 340000 J kg and the specific latent heat of steam is 2,300,000 J/kg and the specific heat capacity of water is 4200 Jkg – ‘k’ calculate the heat needed to change 2kg of ice at 0°C to steam at 100°C.
Two funnels A and B contain crushed ice at 0°C.
Figure 9
The mass of melted ice from each funnel is measured after 11 minutes. The results are shown below.
Mass of melted ice in A = 24g
Mass of melted ice in B = 63g
(i) What is the reason for setting up funnel A?
(ii) Determine the:
III. specific latent heat of fusion of ice.
(i) The heat absorbed by the water
(ii) Heat absorbed by the electric kettle
(iii) The time taken for the water to boil
(iv) How much longer it will take to boil away all the water
(b) A metal of mass 10kg is heated to 1200C and then dropped into 2kg of water . The final temperature of the mixture is found to be 500 C . Calculate the initial temperature of the water .(Specify heat capacity of the metal and water is 450Jkg-1K-1 and 4200Jkg -1 K-1 respectively )
(c) (i) Give the property of water which makes it suitable for use as a coolant in machines
(ii) Formation of ice on roads during winter in cold countries is known to hamper vehicles. State two ways in which the melting of ice may be lowered to solve this problem
(d) Figure 11 shows some ether put in a combustion tube and two glass tubes inserted into the tube through a cork. The combustion tube is then put into a small beaker containing some water and a thermometer dipped in the water.
When air is blown into the ether as shown, the reading in the thermometer lowers. Explain this observation
(b) In an experiment to determine the power of an electric heater, melting ice was placed in a container with an outlet and the heater placed in the ice as shown below. The melted ice was collected.
(i) Other than the current and voltage, state the measurement that would be taken to determine the quantity of heat absorbed by the melted ice in unit time.
(ii) If the latent heat of fusion of ice is L, show how measurement in (i) above would be used in determining the power P of the heater.
(iii) It is found that the power determined in this experiment is lower than the manufacturer’s value indicated on the heater. Explain. (
(c) A mass of wax of 1kg was heated uniformly by a 100W heating element until it melted. The graph below shows how the temperature of the wax varies with time.
(i) Explain what is happening in the region.
AB________________________
BC________________________
(ii) Calculate the specific heat capacity of the wax.
(iii) Calculate the specific latent heat of fusion of wax.
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